Consider the family $f\colon \mathfrak X \to \mathbb C^*$ of elliptic curves over $\mathbb C^*$ with coordinate $t$ given by the affine equation $y^2 = x^3 - t$. Then all the fibres have $j$-invariant $j = 0$, hence they are all isomorphic. In fact, it is easy to see that the family trivializes after the finite étale base change $s \mapsto s^6$.
On the other hand, it is claimed (e.g. in Exercise 1.6 of "Moduli of Curves" by Harris and Morrison) that the family $f$ is not trivial.
How to show this?
One idea would be to show that the family does not have an algebraic/holomorphic section. However I don't know how to do this.
Or one could show that $R^1 f_* \mathbb Z_{\mathfrak X}$ has non-trivial monodromy using the Picard-Lefschetz formula. But this requires doing a semistable reduction first, which boils down to taking the 6-to-1 cover mentioned above and then the monodromy will be trivial because the family is trivial.
One idea is to show that the total space of the family is rational. In other words, we want to show that the surface $$ \operatorname{Spec} \frac{k[x,y,t]}{(x^3-y^2-t)} $$ is rational. This can easily be seen algebraically. At the level of rings, $$ \frac{k[x,y,t]}{(x^3-y^2-t)} \cong k[x,y] $$ where we used the fact that $R[t]/(t-a) = R$ for $a\in R$. In this case, $R=k[x,y]$. Consequently, our surface is isomorphic to $\operatorname{Spec} k[x,y]=\mathbb{A}^2$, so it is rational. (If you prefer a geometric argument, you can project away from a point.)
This proves that the given family is not trivial: Indeed, the total space of the trivial family is isomorphic to the surface $\mathbb{C}^* \times E$ where $E$ is the elliptic curve $y^2=x^3-1$ (since all the fibers are isomorphic elliptic curves). This surface is not rational, because a rational map $\mathbb{P}^2\dashrightarrow \mathbb{C}^*\times E$ composed with the projection $\mathbb{C}^*\times E\to E$ would give a dominant map $\mathbb{P}^2\dashrightarrow E$ which would mean that $E$ is unirational. Any unirational curve is rational (by Luroth's theorem), which is a contradiction (because an elliptic curve have genus 1, so it is not rational).