So I have learned that for a graph to be considered Planar, if it has at least 3 vertices, you can apply the following formula to test for planarity:
number of edges ≤ 3(number of vertices) - 6
also known as $m \leq 3n-6$, where $m$ is the number of edges (the size), $n$ is the number of vertices (the order).
Why is the complete graph known as $K_{3,3}$ (which I have linked for convenience) not considered planar, even though it follows this rule? Is it an exception?
It's not really a test; it's a fact that falls out of a graph if it is planar. So if a graph is planar, then we have $m \leq 3n -6$ ($n$ vertices, $m$ edges). But not all graphs with this property will be planar.
In other words:
$G$ planar $\Rightarrow m \leq 3n-6$
but
$m \leq 3n-6 \nRightarrow G$ is planar.