Excuse me, this is stupid, but I have a short circuit in my head, I can't understand the situation.
Let $k$ be a field, $G$ a finite group, $kG$ the corresponding group algebra and $\delta:G\to kG$ the natural embedding. Let $A$ be a unital associative algebra over $k$ and $\pi:G\to A$ a homomorphism, i.e. a map with the following properties: $$ \pi(a\cdot b)=\pi(a)\cdot \pi(b),\qquad \pi(1)=1,\qquad a,b\in G. $$ Then there is a homomorphism of algebras $\varphi:kG\to A$ such that $$ \varphi\circ\delta=\pi. $$ Consider the kernels of $\pi$ and $\varphi$: $$ {\tt Ker}(\pi)=\{a\in G:\ \pi(a)=1\},\qquad {\tt Ker}(\varphi)=\{x\in kG:\ \varphi(x)=0\}. $$ A question:
What is the connection between ${\tt Ker}(\pi)$ and ${\tt Ker}(\varphi)$? Is it possible to express ${\tt Ker}(\varphi)$ in terms of ${\tt Ker}(\pi)$, and vice versa?
The following is not right in general (see comments), but may be helpful to others looking for a solution.
$\pi$ is a homomorphism (of monoids with unit) from $G$ into the multiplicative monoid of $A$. Since $\pi(a) \cdot \pi(a^{-1}) = \pi(a \cdot a^{-1}) = \pi(1) = 1$, the image of $\pi$ is actually a subgroup, $H$ say, of the multiplicative monoid of $A$. The subalgebra of $A$ generated by $H$ will then be isomorphic to the group algebra $kH$. Let $m = |\ker(\pi)|$ and $n = |H|$, then we have $$ |G| = mn $$ So as $kG$ is $|G|$-dimensional and $kH$ is $m$-dimensional, we have $$ \dim(\ker(\phi)) = |G| - m = (m - 1)n $$ If you enumerate the non-unit elements of $\ker(\pi)$ as $k_1, k_2, \ldots, k_{m-1}$ and pick representatives $g_1, g_2, \ldots, g_n$ for the cosets of $\ker(\pi)$, then the elements $k_ig_j - g_j$ of $kG$ give you $(m-1)n$ linearly independent elements of $\ker(\phi)$ and hence form a basis for $\ker(\phi)$.