Let's assume 1 kilogram is equal to 2.2 pounds.
$1 kg = 2.2 lb$
So we get:
$1/2.2 = lb/kg$
Which means:
$1 : 2.2 = lb : kg$
So if we convert 5 kg to lb and y stands for the pound number, we get:
$1 : 2.2 = ylb : 5kg$
$5kg= y*2.2*lb$
$5(2.2lb)= y*2.2*lb$
$y = 5$
It is really wierd because we all know that it should have been
$kg : lb = 1 : 2.2$
Is there a lack of thinking from me?
Well, if $y$ is the number such that $y\,lb=5\,kg$, then you'd have $y\, lb : 5\,kg = 1:1$, no? Because they are supposed to be the same mass. What you should have is that $y\times lb = 5\times kg$, i.e. $$ y:5=kg:lb=2.2:1$$
Or, as some would say in a rather convoluted way, the numerical values are inversely proportional to units of measure.