I guess the answer is the $n^2\times n^2$ block matrix $diag(B, B, ..., B)$. Where shall I start to prove it? I tried to find the matrix by figuring out the image of the standard basis of $V$, but it gets complicated.
Any idea would be appreciated.
One more question
$\bullet$ Any idea about how to compute $det(L_B)$? I am sure that the answer is $det(B)^n$ if $B$ is invertible.
I found the answer of question $\bullet$ here :)
If we use a standard basis in which the matrix $$ A=\begin{pmatrix} a_{11}&a_{12}&\cdots &a_{1n}\\ a_{21}&a_{22}&\cdots &a_{2n}\\ \cdots\\ a_{n1}&a_{n2}&\cdots &a_{nn}\\ \end{pmatrix} $$ is represented as a vector of components $$ A=\begin{pmatrix} a_{11}\\\cdot\\\cdot \\a_{1n}\\ a_{21}\\\cdot\\\cdot \\a_{2n}\\ \cdots\\\cdots\\ a_{n1}\\\cdot \\\cdot\\a_{nn}\\ \end{pmatrix} $$ than the matrix that represents the transformation $L_B(A)=BA$ is a block matrix of the form $$ \begin{pmatrix} B_{11}&B_{12}&\cdots &B_{1n}\\ B_{21}&B_{22}&\cdots &B_{2n}\\ \cdots\\ B_{n1}&B_{n2}&\cdots &B_{nn}\\ \end{pmatrix} $$ where $B_{ij}$ is a diagonal matrix with as diagonal value the element $b_{ij}$ of the matrix $B$
You can prove this result starting from the case $n=2$ and using induction.