For an isomorphism I let $\phi:W^\perp\to V/W$ be defined as $\phi(x)=[x]$
To show $\phi$ is injective suppose $x\neq y$ for $x,y \in W^\perp$.
Since $W=\{ (x,y,z): x+y+z=0\}$, $(1,1,1)$ is the vector normal to the plane $W$.
And so $x=a(1,1,1)$ and $y=b(1,1,1)$ where $a\neq b$.
Then $x-y=(a-b,a-b,a-b)$ and $a-b+a-b+a-b=3(a-b)\neq 0$
so $x-y \not\in W$ and $[x]\neq [y]$. Thus $\phi$ is injective.
I'm not sure how to show it's onto.
To show $\phi$ is onto, let $[y] \in V/W$
then maybe I have that $y=w+v$ for some vector $w\in W$ and $v\in V$. So that $\phi (w+v)=[w+v]=[y]$?
I think describing V/W geometrically would mean showing $V/W=[span(1,1,1)]$
$W^\perp$ is one dimensional since it's isomorphic to a one dimensional space, namely, $span\{(1,1,1)\}$.
Since $dim(W) = 2$, we have that $dim(V/W) = 1$
You have an injective map, $\phi$, between two one dimensional spaces, $W^\perp $ and $V/W$
Rank nullity says the the dimension of the image of $\phi$ is one and hence is all of $V/W$