If $V$ is a vector field and $\alpha$ is a linear form,
$$ L_V\alpha: X\mapsto V(\alpha(X))-\alpha([V,X]) $$
for every field $X$, is $\mathbb R$-linear, which is trivial since $V$ is a field and $\alpha$ is linear, and $[V,\cdot]$ is also linear. (Is this right?) Also, $L_V:\mathfrak X^*\to\mathfrak X^*$,$ \alpha\mapsto L_V\alpha$ is $\mathbb R$-linear, but I would like to prove that $$ L_V(f\alpha) = V(f)\alpha+ fL_V\alpha, $$ which is like a Leibniz property. Any help?
First of all, $[V, \cdot]$ is $\mathbb{R}$-linear but not $C^{\infty}(M)$-linear. That is, $[V, kW] = k[V, W]$ if $k$ is a constant, but for a non-constant function $f$, $[V, fW] \neq f[V, W]$.
Your description of $L_V\alpha$ is via its action on vector fields, so to deduce something about $L_V(f\alpha)$, you should consider how it acts on a vector field. Replacing $\alpha$ by $f\alpha$ in your formula, we obtain
$$(L_V(f\alpha))(X) = V((f\alpha)(X)) - f\alpha([V, X]).$$
Now, $f$ is a function and $\alpha$ is a one-form, so $f\alpha$ is a one-form which satisfies $(f\alpha)(X) = f\alpha(X)$; as $\alpha$ is a one-form and $X$ is a vector field, $\alpha(X)$ is a smooth function, so the right side of this equality is the product of two smooth functions, $f$ and $\alpha(X)$. Now use the fact that $V$ is a vector field, so it is a derivation of smooth functions (in particular, it satisfies the Leibniz rule).