(The image corresponds to the book "Lie Groups, Lie Algebras, and their Representations" by Varadarajan)
Hello. I have a question regarding Lie groups and Lie algebras. If I have a Lie algebra $\mathfrak{g}$ the theorem mentions that there is a simply connected Lie group $G$ such that its Lie algebra is isomorphic to $\mathfrak{g}$.
Question 1. Is such a group $G$ related to the exponential application? i.e. $G=\left\{\exp(X):X\in\mathcal{G}\right\}$?

(All Lie algebras are finite-dimensional here.) Generally:
These remarks apply in particular to the unique simply connected Lie group with Lie algebra $\mathfrak{g}$. However, generally it's not true that the exponential map is surjective.
Edit: Maybe I've misunderstood your question. Maybe you were asking: can one construct the unique simply connected Lie group $G$ with Lie algebra $\mathfrak{g}$ using the exponential map somehow?
The answer is not obviously yes, since in the absence of a specific Lie group it's not clear what "the exponential map" ought to mean. We can do something like this by first using Ado's theorem to find a faithful representation $\mathfrak{g} \to \mathfrak{gl}(V)$. This means we can apply the ordinary matrix exponential to $\mathfrak{g} \subset \mathfrak{gl}(V)$ which will generate a subgroup of $GL(V)$. This group is not necessarily simply connected, but it does have Lie algebra $\mathfrak{g}$ (this is not obvious but is standard) and we can take its universal cover.