$\lim_{x \to \frac{\pi}{2}} (\pi - 2x) \tan x = $ can this be solved by something like this :
$\pi - 2x = t$
$x = \frac{\pi - t}{2}$
$x \to \frac{\pi}{2}$
$\frac{\pi - t}{2} \to \frac{\pi}{2}$
$t \to 0$
without derivative nor $\cot (\frac{\pi}{2} - x)$
Yes, with your substitution $\pi-2x=t$, we have $$\tan x=\tan\frac{\pi-t}{2}=\tan\left(\frac \pi 2-\frac t2\right)=\cot\frac t2 $$ the limit becomes $$\lim_{t\to 0}t\cot{\frac t2}=\lim_{t\to 0}t\frac{\cos\frac t2}{\sin \frac t2}=2 $$ using $\lim_{y\to 0}\frac{y}{\sin y}=1$ for $y=\frac t2$.