List of Naturally Isomorphic Real Vector Space Pairs

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Let's consider the category of finite dimensional real vector spaces (VS) / inner product spaces (IPS).

Which of the following pairs of isomorphic vector spaces (given appropriate dim constraints), are naturally isomorphic as VS/IPS? Are the natural isomorphisms unique? In the case IPS, is there always a natural isomorphism that is also isometric?

Domain Co-Domain nat. iso. as VS? nat. iso. as IPS? nat. iso. unqiue?
$V$ $V$ ?
$V$ $V^*$ ✔? ?
$V$ $(V^*)^*$ ?
$U⊕V$ $V⊕U$ ?
$U⊗V$ $V⊗U$ ?
$U⊕(V⊕W)$ $(U⊕V)⊕W$ ?
$U⊗(V⊕W)$ $(U⊗V)⊗W$ ?
$U⊗(V⊕W)$ $(U⊗V)⊕(U⊗W)$ ?
$(U,V)$ $U^*⊗V$ ?
$(U⊗V, W)$ $(U, (V,W))$ ?
$ℝ^m⊕ℝ^n$ $ℝ^{m+n}$ if $m+n≤1$? if $m+n≤1$? ?
$ℝ^m⊗ℝ^n$ $ℝ^{m⋅n}$ if $m⋅n∈\{0,1,m,n\}$? if $m⋅n∈\{0,1,m,n\}$? ?
$ℝ^m⊕ℝ^n$ $ℝ^k⊕ℝ^l$ if $\{k,l\}=\{m,n\}$? if $\{k,l\}=\{m,n\}$? ?
$ℝ^m⊗ℝ^n$ $ℝ^k⊗ℝ^l$ if $\{k,l\}=\{m,n\}$? if $\{k,l\}=\{m,n\}$? ?
$ℝ^m⊗ℝ^n$ $ℝ^n⊕…⊕ℝ^n$ if $m≤1$? if $m≤1$? ?

Feel free to suggest other common isomorphic pairs / edit the list.