Here are some list to start with $$\begin{array}{|c|c|c|} \hline \mbox{Space}(S)& \pi_1(S) \\ \hline \mathbb{R}^2&0 \\ \hline \mathbb{S}^1& \mathbb{Z} \\ \hline 1-Torus& \mathbb{Z}\times\mathbb{Z} \\ \hline \end{array}$$ How many more could you add to this list?
Lists of the first fundamental group of spaces.
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You can find a space with fundamental group $G$ for any group $G$. If $G$ has a group presentation $\left<S | R \right>$, form a bouquet of circles with a fixed basepoint, one circle for each element of $S$, and call this $Y$. Attach $2$-cells to $Y$ along the appropriate loop for each relation $r\in R$ (In particular, if $r=s_1^{\pm 1}\dots s_n^{\pm 1}$, then the attaching map $\partial D^2=S^1\to Y$ will attach $S^1$ to the loop $s_1^{\pm 1}\dots s_n^{\pm 1}\in \pi_1 Y=F(S)$, the free group on S). Then the fundamental group of this space is $G$. This is an application of Van Kampen's Theorem for CW-complexes.
For example, take $G=\mathbb{Z}_n = \left<a | a^n\right>$. The $1$-skeleton is just a circle with a fixed basepoint. Attach a $2$-cell to the $1$-skeleton along the loop $a^n$. Then if this space is $X$, $\pi_1 X = \left<a\right> / \left<a^n \right>=\mathbb{Z}_n$.
Some standard examples: