As we know a first order theory $T$ is finitely axiomatizable if there is a finite set $F\subseteq T$ of axioms such that $F\vdash \sigma$ for every $\sigma \in T$.
How we can prove if $\mathsf{ZF}$ is consistent, then $\mathsf{ZF}$ is not finitely axiomatizable? By using the Reflection Theorem or any other if we could use?
You can find the proof in Kunen's famous book "Set Theory: An Introduction To Independence Proofs" (North Holland, 1980). It is Corollary IV 7.7 on page 138, and it does make use of reflection.