I'm trying to show that $M_n(R^{opp}) \cong M_n(R)^{opp}$ as rings. My thought was that $\varphi : M_n(R)^{opp} \to M_n(R^{opp})$ defined by $\varphi (A) = A^{T}$ is the desired isomorphism. But I'm a little confused as to what there is to verify...
Clearly $\varphi^{-1} = \varphi$, so it is bijective, $\varphi (A+B) = (A+B)^{T} = A^{T} + B^{T}$, and $\varphi (A \star B) = \varphi (BA) = (BA)^{T} = A^{T} B^{T} = \varphi (A) \varphi (B)$, where $\star$ is the opposite product of $M_n(R)^{opp}$.
Is that it? Seems like a cheesy proof. I tried consulting some of the users in the chatroom. The only one to proffer a critique was Thorgott. He said that "I don't think $\varphi^{-1} = \varphi$, given that codomain and domain are different." After thinking about this for some time, I don't think this is a problem, because although $M_n(R^{opp})$ and $M_n(R)^{opp}$ denote different rings, the underlying sets are the same.
The entire argument is hidden in the step $(BA)^T = A^T B^T$ and the notation obscures what's going on slightly; on the LHS the matrices are being multiplied in $M_n(R)$ and on the RHS the matrices are being multiplied in $M_n(R^{op})$ (and the statement is false if $R$ is noncommutative and both matrix multiplications are interpreted in the same matrix ring). Once you write out what's going on here in coordinates it should be clear what's going on and what you have to prove.
Maybe the cleanest way to write this proof is to introduce explicit notation for the "identity" map $(-)^{op} : M_n(R) \to M_n(R^{op})$. $\varphi(A)$ should really be defined as $(A^{op})^T = (A^T)^{op}$ (the "opposite transpose"). Now you're no longer sweeping anything under the rug: you need to prove that
$$((BA)^T)^{op} = (A^T)^{op} (B^T)^{op}$$
(now the op's have been properly inserted!) which will then give $\varphi(A \star B) = \varphi(A) \varphi(B)$.
As for Thorgott's objection, this is a notational issue again; write $\varphi_R$ for the transpose map $M_n(R)^{op} \to M_n(R^{op})$ and you'll see that the inverse of $\varphi_R$ is $(\varphi_{R^{op}})^{op}$, where the "op" here has yet another meaning: if $f : R \to S$ is a ring homomorphism then it has an opposite ring homomorphism $f^{op} : R^{op} \to S^{op}$ which on underlying sets is just $f$ again.