Metric and topological structure in matrix Lie algebra

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I am interested in a rather basic question, as I am studying Lie groups.

Let $G$ be a matrix Lie group, say $O(n)$. Consider the Lie algebra $\mathfrak{g}=\mathfrak{o}(n)$.

On the one hand, $\mathfrak{g}$ has some smooth structure (which I don't quite understand yet), and has some topology on it. On the other hand, $\mathfrak{g}$ is just a set of matrices and so it has a natural notion of a metric on it (say as the inherited metric as a subspace of $\mathbb{R}^{n^2}$).

My questions are:

  1. is the topology on $\mathfrak{g}$ compatible with some metric?
  2. In particular, can I interpret the statement that $\exp:\mathfrak{g}\to G$ is a local diffeomorphism, as the fact that the restriction to some ball in $\mathfrak{g}$ around $0$ (rather than just a neighborhood) is a diffeomoprhism on its image?
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The topology on $\mathfrak g$ is the one induced by the distance that you will get from any norm that you define on $\mathfrak g$. Since $\dim\mathfrak g<\infty$, all those norms are equivalent (that is, they all induce the same topology). And, yes, what you wrote about the exponential map is correct.