Given two primes $p$ and $q$ where $q > p$ and a positive integer $k<q$, if $nq+k$ is divisible by $p$ then what's the minimum value of $n$ if one such $n$ exists?
Also do there exist any $k$ such that $nq+k$ is never divisible by $p$ for any $n$? If such $k$ exists how to find that?
For your second question, Dirichlet's theorem on prime in arithmetic progressions tells us that if $q$ does not divide $k$ then there exists $n$ such that $p$ divides $nq+k$.