$\mathbb{Z}/7\mathbb{Z}=\{1,2,3,4,5,6\}$.
$6\times 6=1~{\rm mod}~ 7$ implies $6$ is an element of order $2$; however, we know that $\mathbb{Z}/7\mathbb{Z}\cong C_7$, not containing an element of order $2$.
I found it incredibly confusing, what have I missed? Any help will be appreciated.
$\mathbf Z/7\mathbf Z\simeq C_7$, yes, but $$\{1,2,3,4,5,6\}=(\mathbf Z/7\mathbf Z)^{\color{red}\times}\simeq C_6,$$ hence it has elements of orders $2$ and $3$, as a cyclic (multiplicative) group.