As usual, let $SU(n)$ represent the set of all the $n\times n$ unitary matrices with determinant $1$.
It's easy to show that any matrix $U$ takes the form $U=e^{iA}$ ($A$ is a $n\times n$ traceless hermitian matrix) must belong to $SU(n)$. Vice verse, for any $U\in SU(n)$, can $U$ be written as the form $U=e^{iA}$? How to prove it? Thank you very much.
This follows from the description of the Lie algebra ${\frak{su}}(n)$. The exponential function $\exp\colon {\frak{su}}(n)\rightarrow SU(n)$ is surjective, since the group $SU(n)$ is compact, i.e., every $U$ in $SU(n)$ is of the form $\exp(iH)=e^{iH}$.