Negative Mean Square Error

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For simple random sampling,

I have calculated somemean square errors for ratio-type estimators such as Isaki estimator, and Prasad Singh estimator.

But, Mean Square Errors i obtained are negative. Does MSE eqaul to a negative value? I there a mistake ?

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You have a mistake. MSE can never be negative, because its an expected value of a non-negative random variable (and thus is non-negative itself).