I'm looking for an example of a topological result which is easy to prove using the fundamental group, but hard or impossible elementarily.
First I thought about something like $\mathbb{R}^2\not\cong\mathbb{R}^n$ for $n>2$, but this should be possible to show without using the fundamental group but just simple connectedness.
Do you have any ideas? Thanks!
Edit: What about Brouwer's fixed point theorem; does it have an easy proof without using the fundamental group? If not, I think it would fit.
Brouwer's fixed point theorem can be proved quite elementarily using Sperner's Lemma.
The fundamental group can be used quite effectively to show certain topological spaces are not homotopic (and thus also not homeomorphic). For instance, none of the following spaces are homotopic: The torus, $\mathbb R^2$, projective plane.
With a little bit of the theory of covering spaces, one gets a very short and elegant proof that a free group on two generators contains subgroups that are free groups on any finite number of generators. This result is not terribly hard, but certainly not elementary in group theory.
There is a nice proof of the fundamental theorem of algebra using the fundamental group (essentially using degree theory).