I know that it's duplicate, but , How can I prove it?
I know that must be element "$a$" of order 2, and element "$b$" of order 3. What is the next step? In fact, from what I search it is claimed that if $ba=ab^2$, then the group is $S_3$. Can someone explain to me why?
You have six elements: $e, a, b, b^2, ab, ab^2$. Prove that they are all different.
Then consider what $ba$ is.
$ba$ can only be $ab$ or $ab^2$ because it cannot be any of the others. (Prove it!)
If $ba=ab$, then the group is abelian.
If $ba=ab^2$, then $a \mapsto (12), b \mapsto (123)$ induces an isomorphism with $S_3$.