Let $P_3(\mathbb{C})$ be the complex vector space of complex polynomials of degree $2$ or less. Let $\alpha,\beta\in\mathbb{C}, \alpha\neq\beta$. Consider the function $L:P_3(\mathbb{C}) \mapsto \mathbb{C}^2$ given by
$$L(p)=\begin{bmatrix} p(\alpha) \\ p(\beta)\\ \end{bmatrix}, \text{ for } p\in P_3(\mathbb{C})$$
For the basis $v=(1,X,X^2)$ for $P_3(\mathbb{C})$ and the standard basis $E = (e_1,e_2)$ for $\mathbb{C}^2$. Find the matrix representation $_E[L]_v$ and determine the null space $N(_E[L]_v)$ and find a basis for the ker(L).
I have found the matrix representation:
$$_E[L]_v = [L(v)]_E = [L(1)]_E\ [L(X)]_E\ [L(X^2)]_E = \begin{bmatrix} 1\quad \alpha \quad \alpha^2 \\ 1\quad \beta \quad \beta^2 \end{bmatrix}$$
By using ERO we can reduce the matrix to: $\begin{bmatrix} 1 \quad 0 \quad - \alpha\beta \\ 0 \quad 1 \quad \alpha + \beta \\ \end{bmatrix},$
I am uncertain how to find the null space $N(_E[L]_v)$ and a basis for the kernel.
You're doing good and the matrix is exactly what you found. The reduced row echelon form is $$ \begin{bmatrix} 1 & 0 & -\alpha\beta \\ 0 & 1 & \alpha+\beta \end{bmatrix} $$ as you found. Now you can determine a basis for the null space of the matrix as generated by $$ \begin{bmatrix} \alpha\beta \\ -(\alpha+\beta) \\ 1 \end{bmatrix} $$ and this is the coordinate vector of a polynomial generating the kernel, which is thus $$ q(X)=\alpha\beta-(\alpha+\beta)X+X^2 $$
As a check: this polynomial $q$ has $\alpha$ and $\beta$ as roots and so $L(q)=0$. The kernel has dimension $1$ by the rank nullity theorem.