The first place after the point is sixteenths, so think $.85 = \frac{x}{16}$. So $x=16\cdot(.85)=13.6$. So the first hex digit is $D$. Then keep iterating this process (i.e., multiply the new decimal part by 16, and use the integer part of the result for the next hex digit) until the process terminates or you get repetition.
The first place after the point is sixteenths, so think $.85 = \frac{x}{16}$. So $x=16\cdot(.85)=13.6$. So the first hex digit is $D$. Then keep iterating this process (i.e., multiply the new decimal part by 16, and use the integer part of the result for the next hex digit) until the process terminates or you get repetition.