How would I go about finding numbers x such that x and 1/x are finitely decimally reciprocal and are also close to 1?
I'm not entirely certain how to phrase this question, but take for example 2. 2 and 1/2 can be represented with a finite number of decimal points.
The closest pair to 1 that I have found is 4/5 and 5/4. Are there closer pairs and how would I look for them?
The only rational numbers that have finite decimal representations are those whose denominator has only $2$ and $5$ as its prime factors. (because if $z$ has a finite decimal expansion, then $y=10^k z$ is an integer for some positive integer $k$, and thus $z = y/10^k$)
Thus, the pairs you are looking for are all of the form $2^m / 5^n$ and $5^n / 2^m$.
To see when they're close to 1, it's easier to turn it into an additive problem by taking logarithms: you want
$$ m \ln 2 - n \ln 5 \sim 0 $$
Rearranging, we want
$$ \frac{m}{n} \sim \frac{\ln 5}{\ln 2} $$
so the problem is to find very good rational approximations to $\ln 5 / \ln 2$.
The first few approximations given by continued fractions is: