I am trying to find out how to calculate the number of different relationships there are between all the non-empty cliques that can be made of a given number 'n' of individuals.
Doing this manually (there may be a mistake),
Given a group of 2 people [A,B], I find 1 relation
1 1:1 rels.: A-B
Given a group of 3 people [A,B,C], I find 6
3 1:1 rels.: A-B, A-C, B-C,
3 1:2 rels.: A-BC, B-AC, C-AB
Given a group of 4 people [A,B,C,D], I find 25
6 1:1 rels. (A-B ... C-D)
12 1:2 rels. (A-BC ... D-BC)
4 1:3 rels. (A-BCD, B-ACD ... D-ABC)
3 2:2 rels. (AB-CD, AC-BD, AD-BC)
Given a group of 5 people [A,B,C,D,E], I find 90
10 1:1 rels. (A-B ... D-E)
30 1:2 rels. (A-BC ... E-CD)
20 1:3 rels. (A-BCD ... E-BCD)
5 1:4 rels. (A-BCDE ... E-ABCD)
15 2:2 rels. (AB-CD ... BE-CD)
10 2:3 rels. (AB-CDE ... DE-ABC)
OEIS A333017 seems to correspond with my calculations. Is my problem an analog of "twice the total area of all (open or closed) Deutsch paths of length n", or have I made a mistake in my numbers, or is this a novel sequence?
Your calculations are correct, but guessing that you have the OEIS sequence A333017 is premature. There are several matches, and the correct sequence is A000392, whose nonzero terms begin $1, 6, 25, 90, 301, 966, 3025, \dots$.
This sequence indicates that the number of "relations between two cliques" from a group of $n$ people is a Stirling number of the second kind: $$\left\{\!{n+1 \atop 3}\!\right\} = \frac{3^n - 2 \cdot 2^n + 1}{2}$$ Combinatorially, this counts the number of partitions of $\{1, 2, 3, \dots, n+1\}$ into $3$ nonempty groups. If we ignore the group containing $n+1$, we get two nonempty disjoint subsets of $\{1,2,\dots,n\}$, which are precisely the thing you're counting.
The formula I gave for $\left\{\!{n+1 \atop 3}\!\right\}$ comes from the inclusion-exclusion principle: