If K is a simplicial complex and $\sigma$ a simplex in $K$ that is not a face of any other simplex in $K$.
Then, let $L$ be $K-{\sigma}$.
This is a simplicial complex.
If $\sigma$ has dimension $n$, then, $d_n(\sigma)$ is an $n-1$ cycle and consists of simplices in L, and so, represents a class in $H_{n-1}(L)$. This defines a homomorphism $\phi: \mathbb{Z} \to H_{n-1}(L)$ by sending $1$ to $[d_n(\sigma)]$
I need to find a homomorphism $\psi : H_n(K) \to \mathbb{Z}$ such that the sequence:
$0 \to H_n(L) \to H_n(K) \to \mathbb{Z} \to H_{n-1}(L) \to H_{n-1}(K) \to 0$ is exact with the obvious inclusions.
I understand that, any class, $[\tau]$ in $H_n(K)$, needs to go to $0$ for $\tau \not = \sigma$.
But, I'm not sure where to send $\sigma$. I understand that it's image must be an integer m, say, such that, $m [d_n(\sigma)]$ lies inside the image of $d_n: C_n(L) \to C_{n-1}(L)$
Which means that there needs to be an n-simplex in L , say $\tau$, with boundary, $d_n(\tau)$ such that $[d_n(\tau)] = m [d_n(\sigma)]$. But how is this possible unless $m = 0$?
EDIT: That is, that $\psi$ is trivial. Could I simply argue that this must be the case because $\phi$ is injective?
Have I completely misunderstood what is going on?
Forgive me for the length of the post, and thank you!
Define a map $f:C_n(K)\to\mathbb{Z}$ by sending $\sigma$ to $1$ and every other $n$-simplex to $0$. Since $\sigma$ is not a face of any $(n+1)$-simplex, $f$ vanishes on any boundary, and thus induces a map $C_n(K)/B_n(K)\to\mathbb{Z}$. Restricting this to the subgroup $H_n(K)\subseteq C_n(K)/B_n(K)$, we get a map $\psi:H_n(K)\to \mathbb{Z}$.
You might think this definition can't work, because $\phi\circ\psi$ is supposed to be $0$, but $\phi(\psi([\sigma]))=\phi(1)=[d_n(\sigma)]$. However, this is not a problem, because $[\sigma]$ is not an element of $H_n(K)$ at all: $\sigma$ is just a simplex, not a cycle! You only have to check that $\phi\circ\psi=0$ when evaluated on cycles! You can see that if $c$ is a cycle, then $\phi\circ\psi([c])=m[d_n(\sigma)]$, where $m$ is the coefficient of $\sigma$ in $c$. But in that case, $c=m\sigma+c'$ where $c'\in C_n(L)$, and then $m[d_n(\sigma)]=-[d_n(c')]=0\in H_{n-1}(L)$ since $c$ is a cycle.
(Of course, there are still other things you have to check to prove that this definition of $\psi$ gives an exact sequence, but this much shows that specific the concern you raised is not a problem.)