For every positive integer $s$, let $A_s$ denote the set of the sums of the converging series $\sum\limits_{n=1}^\infty\frac{a_n}{n^s}$ for every periodic sequence of integers $(a_n)$.
Then each $A_s$ is a countable dense subset of the real numbers, and an additive group. The set $A_1$ is in fact a vector space with scalars drawn from the rationals.
I suspect $A_s$ should contain no non-zero rationals (counterexamples are welcome!) but a proof of this would imply that Catalan's number is irrational so attacking that directly should be avoided...
Question Can anything interesting be said about the intersections of these sets? For example, is it the case that $A_s\cap A_t=\{0\}$ for every $s\ne t$?
This question comes from my own musings and it may be open. I suppose this is a risk one always has when asking questions that flirt with the zeta function.
Some Notes: $\zeta(s)\in A_s$, $\eta(s) \in A_s$, $\ln(\mathbb{Q})\subset A_1$.
Generalizations that may be worthy of follow up:
1) Is this just the case for positive real numbers $s\neq t$?
This has now been answered below. This is not the case.
2) If we define $A_s$ with Gaussian integers do we get the same results?
Edit 1 (an effort to spruce this question up): Some Motivations + some cool values
This question didn't get the excitement I expected so I will now add some crazy values! Here are a couple of values from Dirichlet series in $A_1$, $A_3$, $A_5$, $A_7$. We can compute specific values in $A_s$ but when we manage to get exact forms of values in these sets (it seems) invariably this is because of their relationship to Dirichlet Series.
$$f(s,\vec{a})= \sum_{n=1}^\infty{\frac{a_n}{n^s}} $$
Then $$ \begin{array}{c|c|c|c|c|c} f(s,\vec{a}) & \vec{a}=(1,-1) & \vec{a}=(1,0,-1,0) & \vec{a}=(1,1,0,-1,-1,0) & \vec{a}=(1,0,1,0,-1,0,-1,0) \\ \hline %%%%%%%%%%%%%%%%%%%%%%%%%%%%% s=1 & \ln(2) & \frac{\pi}{4} & \frac{2 \pi}{3\sqrt{3}} & \frac{\pi}{2\sqrt{2}} \\ %%%%%%%%%%%%%%%%%%%%%%%%%%%%% s=3 & \frac{3}{4}\zeta(3) & \frac{\pi^3}{32} & \frac{5 \pi^3}{81\sqrt{3}} & \frac{3\pi^3}{64\sqrt{2}} \\ %%%%%%%%%%%%%%%%%%%%%%%%%%%%% s=5 & \frac{15}{16}\zeta(5) & \frac{5 \pi^5}{1536} & \frac{17 \pi^5}{2916\sqrt{3}} & \frac{19 \pi^5}{4096 \sqrt{2}} \\ %%%%%%%%%%%%%%%%%%%%%%%%%%%%% s=7 & \frac{63}{64}\zeta(7) & \frac{61\pi^7}{184320} & \frac{91 \pi^7}{157464\sqrt{3}} & \frac{307 \pi^7}{655360\sqrt{2}} %%%%%%%%%%%%%%%%%%%%%%%%%%%%% \end{array}$$
Column(1) Column(2) Column(3) Column(4) And more
So here are just some specific elements in $A_s$ to get a feeling for these sets.
I sought out an authority of some kind on these matters and I will reproduce the answer below. To summarize, the answer is that my conjecture is the expectation of mathematical community but there doesn't seem to be much in the way of evidence for these expectations.
This comes from an email exchange with Professor Wadim Zudilin who studies these type of mathematical structures. I have added some formatting but really have left the content untouched.
Dear Mason,
I cannot be long in my answer but indeed there are some expectations on how the sets $A_s$ in your notation are structured for positive integers $s$. I assume that $\{a_n\}$ is periodic from the very beginning: $a_k=a_{T+k}$ for all $k=1,2,\dots,$ with $T$ a fixed period. The only $\mathbb{Q}$-linear relations within $A_s$ for $s$ fixed are expected to be those evaluating to $0$ (that is, no rational numbers apart from $0$ can be in the $\mathbb{Q}$-linear span of $A_s$). Furthermore, $A_s$ and $A_t$ are linearly disjoint for $s\ne t$ in the sense that their $\mathbb{Q}$-linear spans intersect at $\{0\}$. A usual language of dealing with $A_s$ is through the Hurwitz zeta function, and there very few results to support those great expectations. There was some work on $A_1$ in relation with Baker's linear forms in logarithms; the latter methods imply that if a $\mathbb{Q}$-linear combination of the elements in $A_1$ is irrational then it is transcendental as well. This is not quite what your question is about, except that we would believe that being irrational means being nonzero.
That's all I can tell you. Don't blame professional mathematicians for not proving somewhat definite towards your (quite natural) expectations: it is extremely hard proving that the numbers are linearly independent over the rationals, because one needs to create for that very good rational approximations to those numbers. And the series in $A_s$ converge too slowly to be easily approximated by the rationals...
Best wishes, Wadim Zudilin