I have been supplied with the following table to indicate one's complement:
This table suggests that -5 in one's complement signed binary equals 10000101. However, guidance found elsewhere suggests that -5 in 'true' one's compliment binary is as follows: 11111010
I'm very confused as to why 10000101 would equal -5, as when you convert -5 to one's complement binary, it equals 11111010. I would appreciate some guidance on how this table interacts/works with known rules about one's complement.

Explanation
One's complement are used to add negative to positive numbers. But there is a one offset error when we compute with the one's complement.
For example if the msb-sign is used for sign bit, the only positives we have now is $0$ to $127$ where sign(msb) bit is 0, that is: 0xxxxxxx.
Likewise we have $-0$ to $-127$, where sign(msb) bit is 1: 1xxxxxxx. For these two representations we spot the one offset error, i.e. we don't need two negative zeros, only one. Read wiki for more explanation.
So we add 1 producing a so-called 2's complement computation. $0$ is $00000000_2$ and $-1$ is $11111111_2$ not $-0$. Here we see one's complement in action. Say we want to make $1$ i.e. $00000001_2$ negative: We invert it using one's complement: $11111110_2$. But this is $-2$, so instead we add $1$ and get $-1$ in two's complement. Now the correct representation is $11111111_2$.
Example
We want to compute: $-5 + 27$. We know that the answer is: $22$.
First convert $5$ to $-5$ using 1's complement:
Now add $27$ to two's complement of $-5$:
Result: