I understand the following:
Assuming that every kid gets at least 1 sweet, then $(1+2+...19+20) = 210 > 200$, which is greater than the $200$ sweets stated. Meaning that the kid who received the $20$ sweets would instead receive $10$ which is the same as another kid.
Would this be enough proof if the question states "Use the pigeonhole principle" to answer the question or is there a formula that I should be applying to prove this?
No, it doesn't meant that the kid who received the $20$ sweets would instead receive $10$. It just means that it is not possible that every kid gets at least one sweet and that no two kids get the same amount.