Suppose that $e^Xe^Y=e^Ye^X$.
It is known that, in general, this equality does not imply $XY=YX$. However, an exercise in Stillwell's Naive Lie Theory Page 154, Exercise 7.6.3 asks to show that $XY=YX$ (My understanding from section 7.6 in the book is that, this exercise requires the implicit assumption that the norms of all matrices involved are small). I would appreciate possibly different hints/solutions for doing this problem.
Edit: Fortunately, I could add the the link to the exercise through googlebooks. Please follow the link for the precise statement of the exercise and the context in which it appears.
"Small norms" may mean that the sought equality holds only approximately. $$ e^{X} e^{Y} = (I + X + \mbox{(negligible)}) (I + Y + \mbox{(negligible)}) = I + X + Y + XY + \mbox{(negligible)} $$ Similarly, $$ e^{Y} e^{X} = I + X + Y + YX + \mbox{(negligible)} $$ Since you asked only for hints, I'll stop here.