Here is an online version of Book 7 of Elements where the following definitions and proposition can be found: https://mathcs.clarku.edu/~djoyce/java/elements/bookVII/bookVII.html
Note: In his books on number theory, Euclid uses the word "measures" in place of "divides".
Definitions:
A unit is that by virtue of which each of the things that exist is called one.
A number is a multitude composed of units. (Thus, a number is a positive integer greater than one.)
A number is a part of a(nother) number, the less of the greater, when it measures the greater;
But (the lesser is) parts (of the greater) when it does not measure it.
Proposition 7.4 says:
Any number is either a part or parts of any (other) number, the less of the greater.
Euclid gives a somewhat long proof of this but isn't it obvious? If $a<b$, $a$ either measures $b$ or doesn't measure $b$. Thus, $a$ is either a part or parts of $b$.
What am I missing?
In Book VII you'll find
When you read these definitions it appears that Euclid's definition is an axiomatic statement:
$\quad$ IF $a \lt b$ THEN $[ \,a \text{ is a part of } b\,] \text{ xor } [\,a \text{ is parts of } b\,]$.
In the guide to the above definitions you'll find
So I think Euclid felt the need for an $\text{XOR}$ algorithm that could decide the matter for any two distinct numbers. Lurking behind this is that he won't be defining rational numbers as an equivalence relation on a set - he needs to calculate a a canonical representation/idea/concept.
Euclid's logic of not regarding $1$ as a number also plays a part in this. My guess is that an attempt was being made to 'compartmentalize' concepts and to avoid trivial statements. For Euclid the number, say five, is a multitude of units. He doesn't want to also say that one is a part of five.
It is interesting how liberating the logic becomes, when, in modern mathematical treatments we don't ignore or shortchange the trivial numbers $1$ or $0$. Euclid would certainly be amazed to see how much things open up once we can all agree on the existence of the empty set.