$$\newcommand{\gcd}{\text{gcd}}$$
Prove: if $d=\gcd(m,n)$ so $\gcd\left(\frac{m}{d},\frac{n}{d}\right)=1$
Intuitively it is obvious, but I am having a hard time to formalize the proof, what I have came to this:
$d=\gcd(m,n)$ so $d|m$ and $d|n$ therefore $m=dx$ and $n=dy$ now if $\gcd\left(\frac{m}{d},\frac{n}{d}\right)\neq 1$ that mean that $m$ and $n$ have a common factor, after the division in $d$ which is the greatest common divisor is contradiction.
Your proof seems fine although you could show the contradiction more evidently.
We want to prove that if $d = \gcd(m,n)$ then $\gcd(m/d, n/d) = 1$.
Assume for the sake of contradiction that this is not the case i.e. $d = \gcd(m,n)$ but $\gcd(m/d, n/d) = k$ where $k > 1$. Then we have:
$$\frac{m}{d} = kx$$
and
$$\frac{n}{d} = ky$$
for some $x$ and $y$, so $m = kdx$ and $n = kdy$ giving:
$$ \gcd(m, n) \geq kd > d $$
which is a contradiction since we assumed $\gcd(m,n) = d$.