Given a homogeneous binary relation $\mathcal{R}$ over a set $A$,and is defied as:
$$\mathcal{R}:=\left\{\left(a,b\right)\mid a\le b\right\}$$
Prove $\mathcal R$ is not symmetric.
I don't understand why $\mathcal R$ is not symmetric,indeed it's symmetric if :
$$\forall a,b \in A:a\le b \implies b\le a $$ Or in other words:
$$\forall a,b \in A$$ one of these are true:
$$a < b \implies b< a $$ $$a < b \implies b= a $$ $$a = b \implies b< a $$ $$a = b \implies b= a $$
As it's seen,the last one is true,and that's why I think the relation is symmetric.
You are wrong.
Your second statement is not equivalent to the first. The first statemtent says that for every pair $a,b\in $A, the statement $a\leq b\implies b\leq a$ is true. The statement $a\leq b\implies b\leq a$ is not the same as
$$(a < b \implies b< a) \lor (a < b \implies b= a)\lor (a = b \implies b< a) \lor(a = b \implies b= a) $$
and you can quite clearly show this by taking $a=1$, $b=2$.
More generally, your argument is based on assuming that, for any collection of logical statements $A, B, C$, the statement $$(A\lor C)\implies(B\lor C)$$ is equivalent to the statement
$$(A\implies B)\lor(A\implies C)\lor(C\implies B)\lor (C\implies C)$$
but this is not the case.
(for clarity, in your argument, $A$ was the statement $a<b$, $B$ was the statement $b<a$, and $C$ was the statement $a=b$)
In fact, if you wanted to write out the logical implication (not that I recommend it), then what you would need to consider is that $$(P\lor Q)\implies (R)$$ is equivalent to:
$$\begin{align}(P\lor Q)\implies R&\sim \neg (P\lor Q)\lor R\\&\sim (\neg P \land \neg Q)\lor R \equiv (\neg P\lor R)\land(\neg q \lor R)\\&\sim (P\implies R)\color{red}{\land}(Q\implies R)\end{align}$$
Note the highlighted $\land$ appearing in the statement which is nowhere in your argument.