I have attempted by using the fact that the even numbers $b$ in a PPT $(a,b,c)$ can be generated using $ b = \frac{s^2 - t^2}{2} $ for any odd integers $s >t \ge 1$ that share no common factors.
We can express any odd numbers as $2k+1$ for some non-negative integers $k$, so:
$$\frac{(2n+1)^2 - (2m^2 + 1)}{2} = \frac{4(n^2 + n - m^2 - m)}{2} \\(2n+1)^2 - (2m^2 + 1)= 2(n(n+1)-m(m+1)) \\ \text{So }\frac{ s^2 - t^2}{2} = 2(2k)=4k \text{ for some integer k }$$
But I think all I did was that I proved that all even numbers $b$ in PPT must be a multiple of 4, rather than proving that all multiples of 4 can appear as b, how would I proceed from this?
What you have to prove is that if I give you a $b$ that is a multiple of $4$, you can express it as $\frac {s^2-t^2}2$ with $s,t$ odd and coprime. As you did, write $b=4k$, then we are looking to have $$8k=s^2-t^2=(s+t)(s-t)$$ One way is just to let $s=t+2$. Then we get $$s-t=2\\s+t=4k\\s=2k+1\\t=2k-1$$ And we know $s,t$ are odd and coprime because if they have a common factor it must divide $s-t=2$