I said that since a 3-dimensional subspace is the span of 3 linearly independent vectors then $U$ and $W$ must be linearly independent.
Since $U$ and $W$ are linearly independent then they span the entire 3-dimensional space.
Since $U$ and $W$ span the entire space, they intersect everywhere.
Therefore, $U \cap W$ is non-trivial for every vector in $\mathbb{R}^3$ except for the null vector.
This was my reasoning but can anybody tell me if my thinking is correct. I feel like I am missing something since I did not make use of $\mathbb{R}^5$.
Recall that $\dim(U\cap V) + \dim(U+V) = \dim U + \dim V=6$. If the intersection was trivial, $U+V$ would have dimension $6$, which of course is impossible.