I have tried to solve the Exercise 8.12, page 227, in Joseph J. Rotman, An Introduction to the Theory of Groups, Fourth Edition, Graduate texts in Mathematics, Springer-Verlag, New York (1995).
The exercise is: Prove that $$PSL(2,9)\cong A_6.$$
Let $G:=PSL(2,9)$, I can see that $|G|=360=2^3.3^2.5$ and it is enough to show that $n_5\ne 36$ (where $n_5$ be the number of Sylow $5-$subgroups) but I stuck here.
Thanks.
All we need to do is to construct a subgroup of index 6 in $PSL_2(\mathbb F_9)$ (indeed, such a subgroup gives a non-trivial homomorphism to $S_6$; since $PSL_2(\mathbb F_9)$ and $A_6$ are both simple of the same order, this is an isomorphism).
Now there is a beautiful geometric construction of a (non-trivial) map $A_5\hookrightarrow PSL_2(\mathbb F_9)$: $A_5$ is the group of rotations of the dodecahedron so we have a map $A_5\hookrightarrow SO(3)\cong PSU_2\subset PSL_2(\mathbb C)$; this map is defined over $\mathbb Z[i,\frac12,\phi]$ (where $\phi$ is the golden ratio), and reduction mod 3 gives a map $A_5\hookrightarrow PSL_2(\mathbb F_3[i]\cong\mathbb F_9)$. Voilà.