In this paper (Pustyl’snikov 1999 Russ. Math. Surv. 54 262), Pustyl’nikov proved the following two theorems
Theorem 1 All the even derivative of $\xi(s) $ at point $s=1/2$ are strictly positive.
Theorem 2 If at least one of those even derivatives were not positive, then RH would be false: in this case there would exist a complex zero $s_1$ ( and it’s mirror image $1-s_1$) that does not lie on the line $\mathrm{Re}(s)$=1/2.
As you can see that this is similar to Li’s criteria.
Question What is the gap between these two theorems and a proof of RH?
Theorem 1 is trivial $$\xi^{(2n)}(1/2) = 2^{2-2n}\int_1^\infty f(x)(\log x)^{2n}dx$$ with $f(x)= x^{1/4} \sum_{n\ge 1}\pi n^2 e^{-\pi n^2 x}(x\pi n^2-\frac32 ) \ge 0$ on $[1,\infty)$
So the theorem 2 doesn't mean anything. When replacing $\zeta(s)$ by the Dirichlet L-function of a quadratic character we'll get that $\xi_\chi$ has similar properties except that $\xi_\chi(1)=0$ so its derivatives can't be all $\ge 0$, therefore I hardly see what the theorem 2 means.