It seems pretty odd to change one of the variable when trying to do some optimization.
You want your volume to be $33$, hence you should not let it be an inequality. when we see $V$, we should directly replace it with $33$.
You do not want to minimize the gradient of the objective function, you want to minimize the objective function.
That is you want to minimize
$$\min _r\frac{66}r+2\pi r^2$$
$$s.t. r > 0$$
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You want your volume to be $33$, hence you should not let it be an inequality. when we see $V$, we should directly replace it with $33$.
You do not want to minimize the gradient of the objective function, you want to minimize the objective function.
That is you want to minimize
$$\min _r\frac{66}r+2\pi r^2$$
$$s.t. r > 0$$