In Devaney's book An Introduction to Chaotic Dynamical Systems, an observation regarding Schwarzian Derivative is given: The fact that each $F^n_4$ has negative Schwarzian derivative allows us to observe that if $K\subset\mathbb{R}$ is any interval on which $(F^n_4)'\neq0$, then the minimum value of $(F^n_4)'(x)$ occurs at one of the endpoints of K.
Why is this true in general?
Here $F_4(x)=4x(1-x)$. But I think the author mean the statement is true for any $f$, not just for $F^n_4$.
It is not true at the Schwarzian is negative for all $f : \mathbb{R} \to \mathbb{R}$. For example, let $f(x)=x+x^3$. Then $Sf(0)=1>0$. However, it is true that
This follow from the following claims:
A. $F_4(x)$ has negative Schwarzian.
B. If $f, g: \mathbb{R} \to \mathbb{R}$ satisfy $Sf(x)<0$ and $Sg(x)<0$, then $S(f \circ g)(x)<0$.
Using these two facts, we can prove Claim 1.
Now we prove the intermediate claims A and B.
Thus, the original claim 1 follows. For completeness, let us prove the composition rule for the Schwarzian, which is a straightforward computation.