The answer to the last part provided is The sum of square of residuals is minimum for points lying on the regression line and so cannot be less than 8.8 for any other line.
Can somebody please explain what this means?
It is almost evident that these points doesn't lie on the given regression line. So if I were to provide a much more accurate regression line, won't the square of sum much more smaller?

This is misleadingly stated. It says "for points lying on the regression line". What it ought to say is that for the line whose slope was specified slope and intercept, the sum of squares of residuals is smaller than it is for any other slope or other intercept.
Note that only seven of the eight pairs are given. You are asked to find the eighth pair.