I got two equations $\ (1) \ $ and $\ (2) \ $ of which the $\ (2) \ $ is said to be related in some relation with $\ (1)$.
$$\ F_t= ma_t \rightarrow - mg \sin \theta = m \frac{d^2 s}{dt^2} \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ (1)$$
$\ s$ is defined to be $\ s=L\theta$, therefore the equation below is obtained:
$$\ \frac{d^2 \theta}{dt^2} = -\frac{g}{L} \sin\theta \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ (2)$$
I don't know how to substitute $\ \theta = \frac{s}{L} \ $ into $\ (1)$ to get $\ (2)$.
p/s: This is the equation of Restoring Force for Simple Pendulum.
Given that, $$ F=-mg\sin \theta=m \frac{d^2 s}{dt^2}$$ so, $$-mg\sin \theta=m \frac{d^2 s}{dt^2}.........(1)$$ $$\text{Again,}~\theta =\dfrac{s}{L}$$ $$\implies s=L\theta$$ substituting the value of s in (1), $$-mg\sin \theta=m \frac{d^2 (L\theta)}{dt^2}$$ $$\implies -g\sin \theta=L\frac{d^2 (\theta)}{dt^2}~\text{[dividing both side by m]}$$ $$\implies \boxed{-\dfrac{g}{L}\sin \theta=\frac{d^2 \theta}{dt^2}}$$