$$A = \{\{\sim\}, *\}$$
find 4 reflexive relations:
$$R_{1} = \{(\{\sim\}, \{\sim\})\}$$
$$R_{2} = \{(*, *)\}$$
$$R_{3} = \{(\{\sim\}, \{\sim\}), (*, *)\}$$
$$R_{4} = \{(\{\sim\}, \{\sim\}), (*, *), (\{\sim\}, *)\}$$
find 2 symmetric relations:
$$R_{1} = \{(\{\sim\}, *), (*, \{\sim\})\}$$
$$R_{2} = \{(*, *)\}$$
find 1 transitive relation:
$$R = \{(\{\sim\}, *), (*, \{\sim\}), (\{\sim\}, \{\sim\})\}$$
I'm not sure about that because of 2 elements in set $A$.
A reflexive relation over $\{\{\sim\},\ast\}$ must include at least both $\langle\{\sim\},\{\sim\}\rangle$ and $\langle\ast,\ast\rangle$ as elements.
Try again. Only $R_3$ and $R_4$ are reflexive.
You have two symmetric relations.
In a transitive relation, if $\langle\{\sim\},\ast\rangle$ and $\langle\ast,\{\sim\}\rangle$ are included, so to must $\langle\{\sim\},\{\sim\}\rangle$.
In a transitive relation, if $\langle\ast,\{\sim\}\rangle$ and $\langle\{\sim\},\ast\rangle$ are included ...