Let $\phi\in D(\Omega)$ and $f\in D'(\Omega)$. If $\phi$ is $0$ in a neighbourhood of $\operatorname{supp}(f)$, then how will we prove that $\langle f, \phi \rangle$ is also $0$? Will it be sufficient if $\phi$ vanishes on $\operatorname{supp}(f)$?
Definition of $\operatorname{supp}(f)$:
Let $f$ be a distribution, and $U$ an open set in $\Bbb R^n$ such that, for all test functions $\phi$ with the support of $\phi$ contained in $U$, $f(\phi) = 0$. Then $f$ is said to vanish on $U$. Hence we can define the support of $f$ as the complement of the largest open set on which $f$ vanishes.
Alternatively, we can say $\operatorname{supp}(f)$ is the subset of $\Bbb R^n$ such that $x \in \operatorname{supp}(f)$, if and only if for all neighbourhoods $\mathcal U$ of $x$, there is $\phi \in D(\mathcal U)$ such that $\langle f, \phi\rangle \neq 0$.
If $\phi$ vanishes only on $\operatorname{supp } f$, then this is not true anymore: Let $f=\delta'$ and and $\phi\in C_c(\mathbb{R})$ with $\phi(x)=x$ for $|x|\leq 1$. Then $\phi(0)=0$, but $f(\phi)= -\phi'(0) = -1$.