Given is $\mathbb{R}^2$ with standard basis $B^2_0$
A "new" basis $B=\left\{\vec{b_1}; \vec{b_2}\right\}$ arises from $B^2_0$ by rotation of $30°$ (clockwise). Determine the change of basis $T^{B}_{B^2_0}$ and the basis vectors $\vec{b_1}$ and $\vec{b_2}$.
So we are in $\mathbb{R}^2$ and we have a standard basis $B^2_0$. Standard matrix is another word for unit matrix I think, so we have $B^2_0 =\begin{pmatrix} 1 & 0\\ 0 & 1 \end{pmatrix}$.
Rotate this by $30°$, we have $B= \begin{pmatrix} \cos(30°) & -\sin(30°)\\ \sin(30°) & \cos(30°) \end{pmatrix} = \begin{pmatrix} \frac{\sqrt{3}}{2} & -\frac{1}{2}\\ \frac{1}{2} & \frac{\sqrt{3}}{2} \end{pmatrix}$
So $\vec{b_1} = \begin{pmatrix} \frac{\sqrt{3}}{2}\\ \frac{1}{2} \end{pmatrix}$ and $\vec{b_2} = \begin{pmatrix} -\frac{1}{2}\\ \frac{\sqrt{3}}{2} \end{pmatrix}$
And $T^{B}_{B^2_0}$ we can solve with Gaussian elimination, right? But I'm more interested to know if I calculated the rotation matrix and the resulting bases correctly?
You seem to misunderstand what is the change of basis matrix from one basis to another: its columns are just the coordinates of the vectors in the new basis, expressed in the initial basis. So it is what you've denoted $B$.
It has the property that it lets you express the initial coordinates of a vector in function of its new coordinates.