Exercise: Prove that $\Gamma\models A$ iff $\Gamma\cup\{\neg A\}$ is not satisfiable.
Proof: We must prove two clauses:
$\Gamma\models A\Rightarrow \Gamma\cup\{\neg A\}$ is not satisfiable
$\Gamma\cup\{\neg A\}$ is not satisfiable $\Rightarrow\Gamma\models A$
Suppose (1) is not true. In such a case, we could make the following claim (by distributing the negation): $\Gamma\models A\text{ and }\Gamma\cup\{\neg A\}\text{ is satisfiable}$
This would require the existence of a valuation v where $v^{*}(A)=\text{T}$ and $v^{*}(\neg A)=\text{T}$ , or -- simplified -- $v^{*}(A)=\text{F}$ . But a sentence cannot be both T and F under the same valuation v of $\mathcal{L}$ , so (1) must be true.
Suppose now that (2) is not true. In such a case, we could make the following claim (by distributing the negation): $\Gamma\cup\{\neg A\}\text{ is not satisfiable}\text{ and }\Gamma\nvDash A$
Since $\Gamma\cup\{\neg A\}$ is not satisfiable, there must be some S where $S\in\Gamma$ , such that $\{S\}\cup\{\neg A\}$ is not satisfiable. For $\{S,\neg A\}$ to be unsatisfiable, S must be A . Trivially, then, $A\in\Gamma$ and so, $\Gamma\models A$. Therefore, (2) must be true. $\Diamond$
I only got 4/10 points for this proof and before I go to office hours I just wanted to ask if I did something obviously wrong/stupid (which might very well be the case). For what it's worth, here are my professor's notes: https://i.stack.imgur.com/4YN00.jpg
I'll prove (2) not by contradiction but by contraposition. Assume $\Gamma$ doesn't entail $A$. Then there is at least one valuation that makes every sentence in $\Gamma$ true but $A$ false. But this same valuation makes every sentence in $\Gamma\cup\left\{¬A\right\}$ true. So $\Gamma\cup\left\{¬A\right\}$ is satisfiable.