According to the book:

I know that it is not possible to write a reflection as a rotation, but from the text it seems that the matrix of the form
$$ A=\left[ \begin{array}{ c c } a & -b \\ b & a \end{array} \right] $$
is the most general form of $O(2)$ since the way it results in $A$ doesn't show any specification of rotation; on the other hand, I can't find any pair of $a,b$ such that
$$ A=\left[ \begin{array}{ c c } 1 & 0 \\ 0 & -1 \end{array} \right]. $$
Why is that?
Thank you.
HINT: $a^2+b^2=1$ and $T(e_1) =(a,b)^t$, give you two solutions not one: $T_1(e_2) =(-b,a)^t$ and $T_2(e_2) =(b,-a)^t$.