Let $E \subset \mathbb{R}$ I claim if the interior is non empty, then it has positive exterior measure. If $E$ has non empty interior, then
$$E \subset\bigcup_{B \subset E \text{open}}B \neq \emptyset$$
As $ B \subset E \subset \mathbb{R}^n$, open sets are of the form
$$(a,b) \times ... \times (a,b) \space n \text{copies}$$
and so we at least have
$$m_*(E)= \inf \sum_{i=1}^nm_*((a_i,b_i))=\sum_{i=1}^n \vert b_i-a_i \vert > 0.$$
So long as $a_i \neq b_i$ which is guantateed since we have nonempty interior. Is this good enough? Trying to go based strictly off definition of interior and exterior measure. Basic definitions.
Outer measure is monotone. There exist $a_i<b_i, i=1,2..,n$ such that $(a_1,b_1)\times (a_2,b_2)\times....\times (a_n,b_n) \subseteq E$ so $m_{*}(E) \geq m_{*} ((a_1,b_1)\times (a_2,b_2)\times....\times (a_n,b_n))=\prod (b_i-a_i) >0$.