I want to solve the following problem. Let $G$ be a finite simple group of even order greater than $2$. Let $n$ be the number of involutions in $G$. Show that $n < |G| / 3$.
Edit: Adding the information I do know about $G$, although not sure whether it is useful for this problem. I can see that $G$ is non-abelian since all abelian simple groups have prime order.
Also before in the text book before this exercise there is a proposition that states that if $t \in G$ is an involution with $m = |C_{G} (t) | $, then $C_{G} (t) $ is a proper subgroup of $G$ and $ |G | \leq ( \frac{1}{2} m(m+1) ) ! $.
Corollary $(2I)$ in the paper "On groups of even order" by Brauer and Fowler says that if $G$ is a simple group which contains $n$ involutions and $t= \frac{|G|}{n}$ then $|G| < \lceil t(t+1)/2 \rceil !$.
This is a simple consequence of Theorem $(2F)$ or Theorem $(2H)$ in that paper so check if something along these lines is in your book. (Which book is it by the way?)
Arguing by contradiction, suppose that $n \geq \frac{|G|}{3}$. Then $t \leq 3$ so $|G|<720$. There are just $5$ non-abelian simple groups of order less than $720$, which are $A_5$, $A_6$, $\operatorname{PSL}_2(7)$, $\operatorname{PSL}_2(8)$ and $\operatorname{PSL}_2(11)$, and these have $15$, $45$, $21$, $63$, and $55$ involutions respectively. In no case does $n \geq \frac{|G|}{3}$ hold, which is a contradiction.
Added. You can use directly Theorem $6.7$ in Rose's "A Course on Group Theory" which says:
Now suppose that $G$ is a finite simple group with precisely $n$ involutions. Since $|Z(G)|=1$ the preceding theorem applies. Note that $|G:H| \neq 2$ since otherwise $H$ is normal in $G$. In fact, the stronger claim is true (which Derek mentioned in his answer), that $|G:H| \geq 5$.
Assume for a contradiction that $n \geq |G|/3$. Then $a := |G|/n \leq 3$, so $G$ has a proper subgroup $H$ such that $|G:H|<6$ by Thm. $6.7$, thus $|G:H|=5$ by the preceding observation. But $|G:H|=5$ is only possible if $G \cong A_5$ (do you see why?) and you are given that $A_5$ has less than $60/3=20$ involutions. That is a contradiction, however, and the proof is complete.