Let $X$ be a set and $A, B \subset X$. Define $\varepsilon:=$ {A,B} $\in$ $\mathcal{P}(X)$ .
How to find the sigma-algebra generated by $\varepsilon$?
I got $\sigma(\varepsilon)$=
{$\emptyset, X, A, A^c, B, B^c, A \cup B, A^c \cup B, A \cup B^c, A^c \cap B^c, A \cap B, A^c \cup B, A \cap B^c, A^c \cap B^c$}.
Besides, how many elements can $\sigma(\varepsilon)$ have at most? I got 14 (elements of the sigma-algebra): $\emptyset, X, A, A^c, B, B^c, A \cup B, A^c \cup B, A \cup B^c, A^c \cap B^c, A \cap B, A^c \cup B, A \cap B^c, A^c \cap B^c.$
Also, how to choose examples of $X, A, B$ such that $\sigma(\varepsilon)$ has less elements than the maximum?
More generally let $A_1,\dots,A_n$ be subsets of $X$.
These sets induce the following "pseudo"-partition of $X$:$$\mathcal P=\{E_1\cap\cdots\cap E_n\mid E_i\in\{A_i,A_i^{\complement}\}\text{ for }i=1,\dots,n\}$$ Observe that every pair of distinct elements of $\mathcal P$ has an empty intersection and that $X$ is covered by the elements of $\mathcal P$. It is not necessarily a partition because $\mathcal P$ might contain the empty set.
Further observe that $\mathcal P$ has at most $2^n$ elements. If $\mathcal A=\sigma(\{A_1,\cdots,A_n\})$ denotes the $\sigma$-algebra generated by the sets $A_1,\dots,A_n$ then evidently $\mathcal P\subseteq\mathcal A$.
Now define:$$\mathcal A'=\{\cup\mathcal V\mid\mathcal V\subseteq\mathcal P\}$$in word: $A$ is an element of $\mathcal A'$ if and only if it can be written as a union of elements of $\mathcal P$.
Since $\mathcal P$ is finite every element of $\mathcal A'$ will be a finite union of elements of $\mathcal P$ so that from $\mathcal P\subseteq\mathcal A$ we can conclude that also $\mathcal A'\subseteq\mathcal A$.
Secondly it is easy to see that $\mathcal A'$ is closed under arbitrary unions (a union of unions is again a union).
Also it is not difficult to see that $\mathcal A'$ is closed under complements.
For that just note that $(\cup\mathcal V)^{\complement}=\cup(\mathcal P-\mathcal V)$.
This tells us that $\mathcal A'$ is a $\sigma$-algebra.
Finally observe that $A_i\in\mathcal P$ for every $i\in\{1,\dots\}$.
As an example note that: $$A_1=\cup\{A_1\cap E_2\cap\cdots\cap E_n\mid E_i\in\{A_i,A_i^{\complement}\}\text{ for }i=2,\dots,n\}$$
These facts together tell us that $\mathcal A'=\mathcal A$.
On base of the fact that $\mathcal P$ has at most $2^n$ elements we find on base of the definition of $\mathcal A'$ that $\mathcal A=\mathcal A'$ has at most $2^{2^n}$ elements (any element of $\mathcal P$ belongs to the union or belongs not to the union).
Your $14$ is wrong and should be $2^{2^2}=2^4=16$.
The sets:
(empty union)
(exactly $1$ element of $\mathcal P$ in the union)
(exactly $2$ elements of $\mathcal P$ in the union)
(exactly $3$ elements of $\mathcal P$ in the union)
(exactly $4$ elements of $\mathcal P$ in the union)