I am considering $3\times 3 $ matrices, one of them is diagonalizable i.e
$$ A=\left[\begin{array}{ccc} 3&0&4\\ 0&-1&0\\ -2&0&-3 \end{array}\right]= \left[\begin{array}{ccc} -1&0&-2\\ 0&1&0\\ 1&0&1 \end{array}\right] \left[\begin{array}{ccc} -1&0&0\\ 0&-1&0\\ 0&0&1 \end{array}\right] \left[\begin{array}{ccc} -1&0&-2\\ 0&1&0\\ 1&0&1 \end{array}\right]^{-1}=P_1DP_1^{-1}. $$ The second one is not diagonalizable, and we have $$ B=\left[\begin{array}{ccc} 1&0&0\\ 0&-1&1\\ 0&0&-1 \end{array}\right]= \left[\begin{array}{ccc} 0&0&1\\ 1&0&0\\ 0&1&0 \end{array}\right] \left[\begin{array}{ccc} -1&1&0\\ 0&-1&0\\ 0&0&1 \end{array}\right] \left[\begin{array}{ccc} 0&0&1\\ 1&0&0\\ 0&1&0 \end{array}\right]^{-1}=P_2JP_2^{-1}. $$ Matrices $A$ and $B$ are called similar if there exists an invertible matrix P such that $ B=P^{-1}AP$.
In my example $A$ and $B$ are not similar, because one of them is diagonalizable and the second is not diagonalizable. I am not sure, that my explaination is proper. I would be grateful for your advices, how to explain that this matrices are not similar.
Since $A$ is diagonalizable matrix and $B$ is a Jordan matrix which is not a diagonal matrix, $A$ and $B$ are not similar.
Or you can say that$$\dim\{v\in\Bbb R^3\mid A.v=-v\}=2,$$whereas$$\dim\{v\in\Bbb R^3\mid B.v=-v\}=1,$$which also proves that $A$ and $B$ are not similar.