For a simply connected $n$-manifold $M\subseteq\Bbb{R}^k$, I want to show that $M$ is orientable.
Take a point $p\in M$ and take an $n$-disc, $D^n$, around $p$ (we can take it as small as we please). Since $S^{n-1}$ is orientable and $M$ (and consequently $TM$) is simply connected, the orientation map $S^{n-1}\to TM$ can be extended to $D^n\to TM$. So around every point there is such a disc. We can construct an atlas (an orientation) out of these.
Does this suffice to prove the claim?
Here is one way to argue. An orientation of a smooth $n$-manifold is a nowhere vanishing section of $\Lambda^n M$ (i.e., a volume form). This is a real line bundle $L\to M$. Put a Riemannian metric on $M$. This defines a metric on $L$ as well. Constructing a nowhere vanishing section of this bundle is the same as constructing a section of the unit sphere bundle $U\to M$ of $L$ (unit sphere in ${\mathbb R}$ is of course the set $\pm 1$). The unit sphere bundle $U\to M$ is a covering map (since the fiber is zero-dimensional). Since $M$ is simply-connected, the bundle $U\to M$ is trivial. Hence, it admits a section.